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Search query: dichloropalladium
4 articles match your search "dichloropalladium"Results 1 to 4, sorted by relevance:
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The crystal structure of the first reported glyoxal–tetraazamacrocycle condensate amine oxide is presented. The sterically hindered oxidized amine binds zinc(II) through the oxygen atom in its folded cleft, with an internal hydrogen bond across the cleft between the oxygen and a protonated tertiary nitrogen.
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The title compound, [Pd2(C12H10O3P)2Cl2(C12H11O3P)2], consists of a dinuclear μ-chloro-bridged palladium unit with two diphenoxyphosphinite groups per Pd atom, linked together by a hydrogen bond. The asymmetric unit contains one half of the molecule, with the other half generated by an inversion centre. The geometry around the P atoms may be described as distorted tetrahedral. Adjacent molecules of the complex are linked by weak C—H
O and C—H
Cl hydrogen bonds. The structure is additionally stabilized by π–π stacking interactions between the aryl rings. These interactions form a herring-bone pattern in the crystal structure.
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The title compound contains a centrosymmetric dimeric cation and it is formed upon slow evaporation of a solution containing bis(acetonitrile)bis[1,2-bis(diphenylphosphino)ethane]palladium(II) bis(tetrafluoroborate) in deuterated chloroform. The anion and the solvent molecule are slightly disordered.
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Some 60 examples of crystal structures are presented which can be better described in space groups different from those used in the original publications.