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Search query: coordinating chloride ions

150 articles match your search "coordinating chloride ions"

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The crystal structure of the title complex, [PdCl(dppe)(INAM)]NO3.CH3CN consists of a PdII metal center in a distorted square-planar environment with hydrogen-bond inter­actions contributing to the crystal packing. An aceto­nitrile mol­ecule completes the asymmetric unit.

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In the crystal structure of the title compound, the central zinc(II) metal atom is surrounded by two N atoms of a bidentate 4,7-meth­oxy-1,10-phenanthroline ligand and two chlorido ligands in a distorted tetra­hedral coordination environment.

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The title compound consists of a chloride anion inter­acting through O—H...Cl hydrogen bonds with a cobalt(II) complex cation, leading to a three-dimensional supra­molecular network.

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The reaction of titanium(IV) chloride with sodium hexa­fluoro­iso­pro­pox­ide, carried out in hexa­fluoro­iso­propanol, produces titanium(IV) hexa­fluoro­iso­pro­pox­ide, which is a liquid at room temperature. Recrystallization from coordinating solvents, such as aceto­nitrile or tetra­hydro­furan, results in the formation of bis-solvate com­plexes. These com­pounds are of inter­est as possible Ziegler–Natta polymerization catalysts.

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Three new cobalt(II) chloride adducts with labile ligands have been synthesized from anhydrous CoCl2. The reactions appear to be sufficiently general to be exploited in a variety of syntheses, including those of magnetically inter­esting single-mol­ecule magnet (SMM) and single-ion magnet (SIM) systems.

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The title coordination complex, [Ni(C6H14N2O)2(H2O)2]Cl2, crystallizes in the P21/n space group. The metal ion displays a slightly distorted octa­hedral geometry. The crystal structure is consolidated by N—H...Cl, N—H...O, C—H...Cl, C—H...O and O—H...Cl hydrogen bonding.

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In the crystal structure of the title compound, the cobalt cations are octa­hedrally coordinated by pairs of μ-1,1-bridging chloride anions and bridging pyridazine ligands and linked into chains propagating along the crystallographic b-axis direction.

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The structure of PfPL1, the first structure of a polysaccharide lyase family 1 subfamily 2 enzyme, reveals a parallel β-helix fold. Structural comparisons reveal insights into substrate recognition and key elements in the catalytic machinery.

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The angular pyridyl-based ligand 3,5-bis­(pyridin-4-ylethyn­yl)pyridine was employed to react with HgCl2 and lead to the formation of a zigzag polymer chain structure.

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The reaction of HgII with the bridging ligand bis­(pyridin-3-ylmeth­yl)sulfane afforded a one-dimensional zigzag chain polymeric structure, with the charge balanced by two coordinated chloride anions. C—H...Cl hydrogen bonds and Hg—Cl...π inter­actions, together with C—H...π hydrogen bonds, stabilize the crystal structure.
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