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Search query: coordinating chloride ions
150 articles match your search "coordinating chloride ions"Results 1 to 10, sorted by relevance:
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The crystal structure of the title complex, [PdCl(dppe)(INAM)]NO3.CH3CN consists of a PdII metal center in a distorted square-planar environment with hydrogen-bond interactions contributing to the crystal packing. An acetonitrile molecule completes the asymmetric unit.
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In the crystal structure of the title compound, the central zinc(II) metal atom is surrounded by two N atoms of a bidentate 4,7-methoxy-1,10-phenanthroline ligand and two chlorido ligands in a distorted tetrahedral coordination environment.
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The title compound consists of a chloride anion interacting through O—H
Cl hydrogen bonds with a cobalt(II) complex cation, leading to a three-dimensional supramolecular network.
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The reaction of titanium(IV) chloride with sodium hexafluoroisopropoxide, carried out in hexafluoroisopropanol, produces titanium(IV) hexafluoroisopropoxide, which is a liquid at room temperature. Recrystallization from coordinating solvents, such as acetonitrile or tetrahydrofuran, results in the formation of bis-solvate complexes. These compounds are of interest as possible Ziegler–Natta polymerization catalysts.
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Three new cobalt(II) chloride adducts with labile ligands have been synthesized from anhydrous CoCl2. The reactions appear to be sufficiently general to be exploited in a variety of syntheses, including those of magnetically interesting single-molecule magnet (SMM) and single-ion magnet (SIM) systems.
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The title coordination complex, [Ni(C6H14N2O)2(H2O)2]Cl2, crystallizes in the P21/n space group. The metal ion displays a slightly distorted octahedral geometry. The crystal structure is consolidated by N—H
Cl, N—H
O, C—H
Cl, C—H
O and O—H
Cl hydrogen bonding.
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In the crystal structure of the title compound, the cobalt cations are octahedrally coordinated by pairs of μ-1,1-bridging chloride anions and bridging pyridazine ligands and linked into chains propagating along the crystallographic b-axis direction.
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The structure of PfPL1, the first structure of a polysaccharide lyase family 1 subfamily 2 enzyme, reveals a parallel β-helix fold. Structural comparisons reveal insights into substrate recognition and key elements in the catalytic machinery.
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The angular pyridyl-based ligand 3,5-bis(pyridin-4-ylethynyl)pyridine was employed to react with HgCl2 and lead to the formation of a zigzag polymer chain structure.
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The reaction of HgII with the bridging ligand bis(pyridin-3-ylmethyl)sulfane afforded a one-dimensional zigzag chain polymeric structure, with the charge balanced by two coordinated chloride anions. C—H
Cl hydrogen bonds and Hg—Cl
π interactions, together with C—H
π hydrogen bonds, stabilize the crystal structure.
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