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electron diffraction
The structure of a CO2 reduction photocatalyst prototype, the first cis-dicarbonyl ruthenium(II) tetrapyrrole complex, has been determined by X-ray and electron diffraction to have an unprecedented seesaw-coordinated biladiene ligand.
research papers
An unprecedented example of an anionic (arene)copper complex has been prepared and structurally characterized in the salt [K(THF)2]2[Cu2(anthracene)2] (THF is tetrahydrofuran), which contains the first homoleptic anthracene complex of a d- or f-block metal bound only to the central ring of anthracene.
data reports
A divalent copper three-dimensional self-penetrated coordination polymer with rob topology, {[Cu2(3-(2-carboxyphenyl)propionate)2(ethylenediamine(bis(nicotinamide)] .5H2O}n, was structurally characterized by single-crystal X-ray diffraction.
research communications
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The structures of fourteen halochalcogenylphosphonium tetrahalogenidoaurates(III) of general formula [R13-nR2nPEX][AuX4] (R1 = t-butyl; R2 = i-propyl; n = 0 to 3; E = S or Se; X = Cl or Br) are presented and compared.
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The molecular structure of the title compound, [Cu(C12H13N2O3)(H2O)2]·[Cu(C12H13N2O3)(H2O)], consists of two different molecules in the asymmetric unit. Both of the structures consist of a tridentate ligand synthesized from L-valine and salicylaldehyde, and one water molecule or two water molecules coordinating to CuII.
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The coordination polyhedron of the Cd2+ ion in the title compound is a CdN2O5 pentagonal bipyramid formed by two bidentately coordinated carboxylic groups of different anions, one water molecule and two pyridine molecules. In the crystal, polymeric chains propagate along the [1
1] direction; the chains are linked by hydrogen bonds and π–π stacking interactions into a three-dimensional network.
1] direction; the chains are linked by hydrogen bonds and π–π stacking interactions into a three-dimensional network.research communicationsOpen access
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In the crystal structure of the title compound, [Zn(cyclam)]2+ cations and SbS43– anions are present, which are linked to acetonitrile and water solvate molecules via intermolecular hydrogen bonding.
CHEMISTRY | CRYSTENG
A comprehensive review of hybrid lead halide perovskites based on [PbX4]∞ layers is presented. We use a crystallographic approach based on symmetry mode analysis to systematize key types of distortions, particularly octahedral tilting and layer shifts, in this extensive and diverse family of materials.
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The structures of five gold complexes involving piperidine or pyrrolidine, either as neutral ligands or protonated counter-cations, are presented.
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The title compound forms a supramolecular dimeric entity via [O—H—O]− negative charge-assisted hydrogen bonds (–CAHB) following a reaction with benzyltrimethylammonium fluoride salt.
