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Search query: Thomas-Reiche-Kuhn sum rule
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X-ray spectroscopy for functional materials
Normalization of XANES data to the spectral area is shown to be a viable normalization method with an error of a few percent as evaluated by comparison with calculated spectra and spectra normalized to the edge-jump.
research papers
The absorption coefficient of X-rays in germanium was measured for 32 wavelengths in the interval 2.3 Å > λ > 0.3 Å (λK = 1.12 Å). A detailed analysis is given, including a comparison with theoretical expressions and a calculation of the oscillator strength for the K-electrons. Agreement between theory and experiment is remarkable. Hydrogen-type wavefunctions give gK = 1.28 for the dipole oscillator strength. A calculation based on the Thomas–Reiche–Kuhn sum rule and Hartree–Fock type wavefunctions gives gK = 1.29, while the authors' experimental value is gK = 1.27± 0.02.