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In the title compound, [Cu(C15H11N3O3)(C10H8N2)], the CuII atom is five-coordinated in a distorted square-pyramidal CuN3O2 geometry. The basal positions are occupied by three donor atoms from the tridentate Schiff base ligand and by one N atom from the 2,2′-bipyridine ligand. The axial position is occupied by the other N atom of the 2,2′-bipyridine ligand. The crystal structure is consolidated by weak C—H
O hydrogen bonds. In addition, π–π interactions between adjacent pyridine rings (centroid–centroid distances = 3.238 and 3.313 Å) may also stabilize the crystal packing.
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In the title compound, C6H16NO3+·C7H4NS2−, the cations and anions are connected by O—H
N and O—H
S hydrogen bonding. Weak C—H
O hydrogen bonding between adjacent cations helps to stabilize the crystal structure.
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