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metal-organic compounds
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In the title compound, [CoRu(C5H5)(C16H9)(C17H14P)2]PF6, the RuII atom is coordinated by a cyclopentadienyl ring in an η5-mode, one C atom from a 4,4′-diethynyl-1,1′-biphenyl ligand and two P atoms from a chelating 1,1′-bis(diphenylphosphanyl)cobaltocenium ligand, giving a three-legged piano-stool geometry. In the crystal, weak C—HF hydrogen bonds link the complex cations and hexafluoridophosphate anions into a three-dimensional supramolecular structure.