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Two structural isomers, 3,6-bis(2-chlorophenyl)-1,4-dihydro-1,2,4,5-tetrazine, (I), and 3,5-bis(2-chlorophenyl)-4-amino-1H-1,2,4-triazole, (II), both C14H10Cl2N4, form chain-like structures in the solid state, stabilized by N-H
N and N-H
Cl hydrogen bonds. A contribution from weak interactions to the strong hydrogen-bond network is observed in both structures. The secondary graph sets for intermolecular hydrogen bonds [
(11) for (I) and
(12) for (II)] indicate the similarity between the networks.
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![R_2^2](http://journals.iucr.org/c/issues/2004/01/00/sk1670//teximages/sk1670fi1.gif)
![R_2^2](http://journals.iucr.org/c/issues/2004/01/00/sk1670//teximages/sk1670fi1.gif)