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56 citations found for Suescun, L
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The structure of catena-[tris(μ4-benzene-1,4-dicarboxylato)-tetrakis(μ1– dimethylformamide-κ1O)-trinickel(II)], C36H40N4Ni3O16, has been determined in the monoclinic P21/n space group. The compound has a two-dimensional coordination network structure and it is of interest with respect to lithium-ion battery applications. Hirshfeld surface analysis was performed to characterize interplanar interactions. The structure exhibits disorder of coordinated solvent molecules.
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The title compounds, 5-ethylthio-3H-1,2-dithiole-3-thione, [C5H6S4 (2)], and 5-methylthio-3H-1,2-dithiole-3-thione, [C4H4S4 (3)], crystallize in space groups C2/c and P21/n, respectively. The molecules are planar, with heterocyclic characteristics similar to those shown by other members of the 3H-1,2-dithiole-3-thione family. The striking difference between the corresponding melting points [340-341 K for (2), 438-440 K for (3)] does not seem to arise from the rather similar main intermolecular interactions but rather from apparently much weaker ones.
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The effect of Pr on the crystal structure of BaCe1 − xPrxO3 − δ was studied. Anomalous X-ray diffraction (AXRD) was used to determine the Pr occupancy in Ba and Ce sites. The structural parameters were correlated with H-ionic conductivity and electron transport.
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Three cis nickel-dithiocyanate (SCN) complexes with different N,N'-bidentate bases have been prepared and their crystal structures determined: bis(2,2'-bipyridine-N,N')bis(thiocyan-ato-N)nickel(II), [Ni(SCN)2(C10H8N2)2], bis(1,10-phenanthroline-N,N')bis(thiocyanato-N)nickel(II), [Ni(SCN)2(C12H8N2)2], and bis(2,9-dimethyl-1,10-phenanthroline-N,N')bis(thiocyanato-N)nickel(II) monohydrate, [Ni(SCN)2(C12H8N2)2]·H2O. Distortions due to ligand size are discussed.
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The title compound, C15H15ClN2O7S, which was synthesized and characterized as the acetoxylmethyl ester of 4-chloro-N-furfuryl-5-sulfamoylanthranilic acid (furosemide) and is an absorption furosemide prodrug. The molecule has been crystallized in a triclinic unit cell and the space group is P
. The crystal structure is stabilized by one intramolecular and two intermolecular hydrogen bonds.
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The title compound, [Cu(C5H8NO2)(C9H10NO2)(H2O)]·H2O, is formed by the chelate coordination of L-prolinate and L-phenylalaninate anions. Both ligands bind through carboxylate O and amine N atoms to the CuII atom in a trans arrangement. The square pyramid is completed by an aqua ligand in the apical position.
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Both title compounds, [Cd(SO4)(C12H8N2)(H2O)2]n and [Cd(SO4)(C14H12N2)(H2O)2]n, respectively, are polymeric and present the Cd atoms in very similar octahedral environments, provided by the bidentate organic ligand (phenanthroline/dimethylphenanthroline), two aqua molecules and two O atoms from two translationally related sulfate groups, which thus act as links in the resulting polymeric chains.
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The crystal structure of divanillin was solved and refined from laboratory powder X-ray diffraction data. The crystal structure is composed of an intricate diamond-type arrangement of four interpenetrating hydrogen-bonded networks that explains the different solubilities of the freshly synthesized material and the product aged for 15 min in the mother liquor.
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The crystal structure of a racemic benzazepine derivative shows an infrequent kind of substitutional disorder where a conformer of one enantiomer replaces the equivalent conformer of the other enantiomer.
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The crystal structure of 1,3-bis(1H-benzotriazol-1-ylmethyl)benzene shows an interesting three-dimensional assembly influenced by its non-planar molecular conformation.
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The crystal structure of a homocoupled compound with absolute configuration 3aR,3′aR,7aS,7′aS was determined. The molecule contains two similar moieties composed of two fused rings. Its supramolecular structure is controlled mainly by C—H
O interactions.
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The tetrahydro-1-benzazepine nucleus is considered to be a good scaffold for the development of novel molecules which can exhibit bioactivity. In this work, we report the crystallographic study of five new compounds with potential antiparasitic properties against Trypanosoma cruzi and Leishmania chagasi.