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5 citations found for Son, J.H.
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The crystal structure of human dual-specificity protein tyrosine phosphatase 18 provides the structural basis for the unusual catalytic activity at high temperature.
metal-organic compounds
Open access
The title compound, [Li2(C18H22BO)2(C6H7N)2], is a lithium dimesitylboroxide dimer in which the lithium cation is also coordinated by one molecule of 2-methylpyridine. At the core of the structure is an Li2O2 four-membered ring. The structure is centrosymmetric with an inversion centre midway between two Li atoms. Intermolecular C—Hπ interactions and π–π interactions between the 2-methylpyridine rings exist [centroid–centroid distance = 3.6312 (16) Å].
organic compounds
Open access
The title compound, C36H44B2O·0.5CH2Cl2, contains an almost linear O—B—O linkage [177.23 (15)°] and approximately orthogonal [interplanar angles 89.49 (5) and 80.77 (4)°] trigonal planar B centers, consistent with the previously reported non-solvated structure [Cardinet al. (1983). J. Chem. Res. (S), p. 93]. Intermolecular C—Hπ interactions exist between mesityl groups, with a C—Hcentroid separation of 3.6535 (18) Å. The dichloromethane molecules lie on twofold rotation axes.
organic compounds
Open access
The title compound, C9H7IN+·Cl−·2H2O, was obtained during the synthesis of 8-iodoquinoline from 8-aminoquinoline using the Sandmeyer reaction. The 8-iodoquinolinium ion is almost planar. Solvent water molecules and chloride ions form a hydrogen-bonded chain along the c axis via O—HCl links. The 8-iodoquinolinium ions, which are packed along the c axis with cationic aromatic π–π stacking (centroid–centroid distance = 3.624 Å), are linked to the chain via N—HO hydrogen bonds.
organic compounds
Open access
The title compound, C9H7IN+·I3−·C4H8O, was synthesized from 8-aminoquinoline using the Sandmeyer reaction. The 8-iodoquinolinium cation is essentially planar and the triiodide ion is almost linear. N—HO hydrogen bonds, and intermolecular II [3.7100 (5) Å] and IH interactions, between the cation, anion and solvent molecules result in the formation of sheets oriented parallel to the (03) plane. Between the sheets, 8-iodoquinolinium and triiodide ions are stacked alternately, with IC distances in the range ∼3.8–4.0 Å.