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11 citations found for Olivier, J.

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Acta Cryst. (1996). A52, C289
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The structure of [Au(C4H5NS)2]CF3SO3 reveals essentially linear cationic gold(I) units [C11—Au—C21 175.8 (7)°]. These linear cations are aggregated through alternating Au...Au interactions [3.1926 (11) and 3.4830 (10) Å] to form chains of Au atoms parallel to the c axis.

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The Au centres in the crystal structure of [Au(C4H5NS)2]2[ZnCl4]0.5.0.5CH2Cl2 approach linear coordination [C-Au-C bond angle 179 (1)°]. Monomeric cations connecting through Au...Au interactions [3.330 (2) Å] form dimeric units that link through hydrogen bonds to the tetrachlorozincate anions. Dichloromethane is present as non-bonded and disordered solvent of crystallization.

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