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The structures of a six- and a seven-membered tellurium- and nitrogen-containing (Te—N) heterocycle represent the first structurally characterized members of their respective classes. When compared to their sulfur analogs, they exhibit slightly greater deviations from planarity to accommodate the larger chalcogenide atom. Intermolecular N—H
O hydrogen bonding forms centrosymmetric
(8) dimers in the six-membered hetereocyclic compound and chains in the seven-membered hetereocyclic compound, while intermolecular Te
O contacts exist in the former.
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![R_{2}^{2}](http://journals.iucr.org/c/issues/2016/01/00/sk3604//teximages/sk3604fi1.gif)
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