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metal-organic compounds
The trimetallic compound catena-poly[dipotassium(I) [bis(2,2′-bipyridine)di-μ3-trifluoroacetato-dodeca-μ2-trifluoroacetato-diplatinum(II)octasilver(I)]], K2[Pt2Ag8(C2F3O2)14(C10H8N2)2], forms an extended structure in the solid state. Electrostatic interactions involving the K+ ions play a key role in the formation of the extended structure in three dimensions. The AgI ions form one-dimensional coordination polymers, with alternating Ag2 and Ag6 units linked by CF3CO2− ligands. PtPt interactions perpendicular to the one-dimensional polymerization axis provide another element of long-range order, and electrostatic interactions with K+ ions provide connectivity between adjacent polymeric structures.