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Two coordination polymers with distinct structures have been prepared under hydrothermal conditions, based on mixtures of benzene-1,3,5-tricarboxylic acid and trans-1-(pyridin-3-yl)-2-(pyridin-4-yl)ethene, together with two different d10 metal ions. Both compounds exhibit good photocatalytic properties in the decomposition of the organic dye contaminant of rhodamine B.
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A three-dimensional cadmium(II) supramolecular framework was prepared by the hydrothermal reaction between Cd(NO3)2·4H2O, 1,4-bis(pyridin-4-yl)buta-1,3-diene and adipic acid. This supramolecular architecture is formed by the interlinkage of a threefold interpenetrating diamondoid coordination network through O—H
O hydrogen-bonding interactions.
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