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6 citations found for Guillet, G.L.

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A nickel(II) cation and two lithium(I) cations are coordinated by two bridging N,N′-(pyridine-2,6-di­yl)bis­(tri­methyl­silyl­amide) ligands. The LiI cations are solvated by tetra­hydro­furan. This complex is a unique example of a heteromultimetallic complex combining an alkali metal and a transition metal.

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A novel family of four 1-bromo-2,6-bis­{[(λ5-phosphanyl­idene)imino]­meth­yl}benzene ligands has been synthesized and each ligand has been com­plexed with nickel(II). The phosphinimine substituents incrementally change from all-phenyl to all-cyclo­hexyl across this family and these ligands represent a useful opportunity to investigate the impact of changing sterics on com­plex structure and reactivity.

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A lithium cation is coordinated by 2,6-bis­(tri­alkyl­silyl­amino)­pyridine and diethyl ether and forms a centrosymmetric dimer.

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A K+ cation is coordinated to a monoanionic 2,6-bis­(tri­methyl­silyl­amino)­pyridine and an 18-crown-6 macrocycle. The complex forms a monomer unlike other related complexes of potassium with similar tri­alkyl­silyl­pyridine ligands and crown ethers.

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The title structure crystallizes in a triclinic unit cell as an ion pair with a single disordered solvent mol­ecule. Hydrogen bonding is observed between the carb­oxy­lic acid moiety and the tetra­hydro­furan solvent.

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