search results
results of search on CRYSTALLOGRAPHY JOURNALS ONLINE
2 citations found for Facco, J.
Search for Facco, J. in the World Directory of Crystallographers
Results 1 to 2, sorted by name:
![c logo](https://journals.iucr.org/logos/jicons/c_36x36.png)
The structure of the title compound, [PtCl2(C5H5N)(C2H6S)], consists of discrete molecules in which the Pt-atom coordination is slightly distorted square planar. The Cl atoms are trans to each other, with a Cl—Pt—Cl angle of 176.60 (7)°. The pyridine ligand is rotated 64.5 (2)° from the Pt square plane and one of the Pt—Cl bonds essentially bisects the C—S—C angle of the dimethyl sulfide ligand. In the crystal structure, there are extensive weak C—H
Cl interactions, the shortest of which connects molecules into centrosymmetric dimers. A comparison of the structural trans influence on Pt—S and Pt—N distances for PtS(CH3)2 and Pt(pyridine) fragments, respectively, in square-planar PtII complexes is presented.
![...](/logos/entities/ctdot_rmgif.gif)
![c logo](https://journals.iucr.org/logos/jicons/c_36x36.png)
The first structurally characterized alkali metal phosphonate, the title compound, [K2(C6H6O3P)2(C3H7NO)(H2O)]n, has a complex structure, with layers parallel to the crystallographic bc plane consisting of two crystallographically independent K atoms sandwiched between the three types of ligands present in the structure, viz. water molecules, dimethylformamide molecules and two crystallographically independent phenylphosphonate ligands. Six O atoms coordinate to one K atom and seven to the other. The interlayer distance is 15.327 (4) Å. The K—O distances are in the range 2.739 (2)–2.932 (2) Å for the seven-coordinate K atom and 2.650 (2)–2.821 (2) Å for the six-coordinate K atom.