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The cations in the title salt show π-stacking. The chloride anions, together with the water molecules, form hydrogen-bonded zigzag chains.
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Two isomers of the molybdenum(II) complex Mo(CO)(C2Me2)(S-Phoz)2 [S-Phoz is 2-(4,4-dimethyloxazolin-2-yl)thiophenolate] have been synthesized and characterized by X-ray diffraction at 100 K and by spectroscopy (NMR and IR). They show quite different Mo—N and Mo—S distances.