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The ambient hydration of the aluminophosphate JDF-2 to AlPO-53(A): insights from NMR crystallography
Using multinuclear solid-state NMR spectroscopy and first-principles DFT calculations, we examine the slow ambient hydration of the AEN-type aluminophosphate, JDF-2, to AlPO-53(A). We propose a modified version of the published structure of AlPO-53(A), with reorientation of the methylammonium cations and partial occupancy of the water sites.