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The structures of the palladium and platinum complexes of 4,4′-bis[(2,2-difluoroethoxy)methyl]-2,2′-bipyridine are isomorphous and have –C(Hα)2OC(Hβ)2CF2H side chains with H-atom donors at the α and β sites. Molecules are associated into dimers and the dimers form columns, with alternating dimers reinforced by C—H
Cl hydrogen bonds and C—Hβ
F(—C) interactions.
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