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metal-organic compounds
The structures of trans-bis[2-(aminomethyl)pyridine-![[kappa]](/logos/entities/kappa_rmgif.gif)
2N,N']bis(saccharinato-N)zinc(II), [Zn(C7H4NO3S)2(C6H8N2)2], (I), and [2-(aminoethyl)pyridine-2N,N']bis(saccharinato-N)zinc(II), [Zn(C7H4NO3S)2(C7H10N2)], (II), exhibit octa- and tetrahedrally coordinated ZnII atoms, respectively. The diamine ligands behave as N,N'-bidentate ligands, while saccharinate (sac) is coordinated through the N atom. In (I), the complex lies about an inversion centre with the Zn atom disordered and displaced by 0.256 (2) Å from a centre of symmetry towards a sac N atom. The crystal structure of (I) is stabilized by N-H
O hydrogen bonds and the crystal packing of (II) is determined by hydrogen bonding as well as weak ![[pi]](/logos/entities/pi_rmgif.gif)
- stacking interactions between the sac ligands.
2N,N']bis(saccharinato-N)zinc(II), [Zn(C7H4NO3S)2(C6H8N2)2], (I), and [2-(aminoethyl)pyridine-2N,N']bis(saccharinato-N)zinc(II), [Zn(C7H4NO3S)2(C7H10N2)], (II), exhibit octa- and tetrahedrally coordinated ZnII atoms, respectively. The diamine ligands behave as N,N'-bidentate ligands, while saccharinate (sac) is coordinated through the N atom. In (I), the complex lies about an inversion centre with the Zn atom disordered and displaced by 0.256 (2) Å from a centre of symmetry towards a sac N atom. The crystal structure of (I) is stabilized by N-HO hydrogen bonds and the crystal packing of (II) is determined by hydrogen bonding as well as weak - stacking interactions between the sac ligands.
