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organic compounds
The title compound, C32H43NO4·CH4O·H2O, has a nearly planar cyano-enone A ring in an otherwise normal oleanane triterpenoid. Rings A, B and C are non-chairs, but rings D and E adopt essentially cyclohexane chair conformations. The structure clearly establishes the C-D-E ring stereochemistry as trans-syn-cis, as predicted from a nuclear Overhauser effect (NOE) NMR measurement.