Crystal structure of (2,4-di-tert-butyl-6-{[(6,6′-dimethyl-2′-oxido-1,1′-biphenyl-2-yl)imino]methyl}phenolato-κ³O,N,O′)bis(propan-2-olato-κO)titanium(IV)

In the mononuclear Ti^IV title complex, [Ti(C₂₉H₃₃NO₂)(C₃H₆O)₂], the TiNO₄ coordination polyhedron comprises an N-atom and two O-atom donors from the dianionic Schiff base ligand and two O-atom donors from monodentate isopropoxide anions. The stereochemistry is distorted trigonal–bipyramidal with the N-donor in an elongated axial site [Ti—N = 2.2540 (17) Å], the O-donors having normal Ti—O bond lengths [1.7937 (14) Å (axial)–1.8690 (14) Å]. In the crystal, C—H...π inter­actions link mol­ecules into centrosymmetric dimers.