Download citation
Download citation

link to html
In the mononuclear title complex, [HgCl2(C20H21N3)], synthesized from the quinoline-derived Schiff base N1,N1-diethyl-N4-(quinolin-2-yl­methyl­idene)benzene-1,4-di­amine (QMBD), the coordination geometry around the Hg2+ atom is distorted tetra­hedral, comprising two Cl atoms [Hg—Cl = 2.3654 (19) and 2.4394 (18) Å] and two N-atom donors from the QMBD ligand, viz. one imine and quinoline [Hg—N = 2.334 (5) and 2.340 (5) Å, respectively]. In the crystal, weak C—H...Cl hydrogen bonds and weak π–π aromatic ring stacking inter­actions [minimum ring-centroid separation = 3.680 (4) Å] give an overall three-dimensional network.

Download citation
Download citation

link to html
In the title phospho­nate, C19H21O9P, the dihedral angle between the benzene rings is 63.33 (3)°, and the P atom has a distorted tetra­hedral geometry, with angles in the range 101.30 (6)–120.38 (6)°. No significant inter­molecular inter­actions are observed in the crystal structure, and π–π inter­actions between symmetry-related benzene rings are beyond 4 Å.

Download citation
Download citation

link to html
In the title compound, C17H12F3NO4S, the heterocyclic thia­zine ring adopts a half-chair conformation and the dihedral angle between the benzene rings is 43.28 (9)°. The α,β-unsaturated C=C group is inclined at an angle of 21.0 (3)° to the benzene ring of the benzo­thia­zine moiety. In the crystal, inversion dimers linked by pairs of carb­oxy­lic acid O—H...O hydrogen bonds generate R22(8) loops. Each of the F atoms accepts a Ca—H...F (a = aromatic) hydrogen bond from an adjacent mol­ecule, resulting in (001) sheets.
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds