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In the title compound, {[Pr(C14H8O5)(C14H9O5)(H2O)2]·H2O}n, the PrIII cation is eight-coordinated by six carboxyl O atoms from both a monoanionic 4-(4-carb­oxy­phen­oxy)benzoate and a dianionic 4,4′-oxydibenzoate ligand (four bridging with two from a bidentate chelate inter­action), and two O-atom donors from water mol­ecules. A single water mol­ecule of solvation is also present. The complex units are linked through carboxyl O:O′ bridges giving a two-dimensional sheet polymer lying parallel to (001). An overall three-dimensional network structure is generated through inter­molecular carb­oxy­lic acid and water O—H...O hydrogen bonds and weak C—H...O inter­actions.
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