organic compounds
Open access
In the title compound, C8H10Cl2N4O, the dichloro-substituted triazine ring and the quasi-plane of the five-membered dimethyl-substituted oxazolidine unit, in which the O atom lies 0.228 (1) Å out of the least-squares plane, are close to being coplanar [dihedral angle = 4.99 (10)°]. In the crystal, molecules are linked by intermolecular C—HCl interactions, forming chains extend along the a axis. Also present are weak π–π interactions between triazine rings [minimum ring centroid separation = 3.7427 (11) Å].
organic compounds
Open access
In the title molecular salt, C5H9N2+·C7H3N2O7−, the roughly planar anion (r.m.s. deviation = 0.120 Å) has been deprotonated at the phenol group. An intramolecular O—HO hydrogen bond in the anion generates an S(6) ring. In the crystal, the components are linked by cation-to-anion N—HO and N—H(O,O) hydrogen bonds, generating [010] double chains. Weak C—HO interactions consolidate the packing.