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In the title compound, C16H16BrN, the tricyclic carbazole system is essentially planar (r.m.s. deviation of all non-H atoms = 0.010 Å). The dihedral angle between the two outer carbazole rings is 1.1 (3)°. There are no directional inter­molecular contacts in the crystal packing.

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The title compound, C12H10BrN3, is essentially planar (r.m.s. deviation of all non-H atoms = 0.0174 Å), with a dihedral angle of 0.5 (2)° between the two aromatic rings. In the crystal, mol­ecules are linked by weak N—H...N inter­actions, forming a zigzag chain running parallel to [001].

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In the title benzoate derivative, C14H9N3O8, the benzene rings form a dihedral angle of 87.48 (5)°. The central ester unit forms an angle of 19.42 (7)° with the methyl­benzene ring, indicating a significant twist. In the crystal, the mol­ecules are linked by weak C—H...O inter­actions forming a helical chain along [010].

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In the title compound, C14H9N3O8, the benzene rings form a dihedral angle of 69.02 (5)°. The central ester group is rotated by 25.86 (9)° relative to the p-tolyl group. In the crystal, the mol­ecules are linked by C—H...O inter­actions into helical chains along [010].

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In the title compound, C21H18O4, the outer benzyl rings are disordered over two resolved positions in a 0.50 ratio. The O—CH2 groups form dihedral angles of 4.1 (2) and 10.9 (4)° with the central benzene ring, adopting a syn–anti conformation with respect to this ring. In the crystal, the mol­ecules are linked by O—H...O hydrogen bonds and weak C—H...O inter­actions, forming chains along [010].
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