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The asymmetric unit of the title iron hybrid fluoride, (C3H12N2)2[FeF6]F·3H2O, contains two propane-1,3-diamin­ium [(H2dap)2+] cations, an octa­hedral [FeF6]3− anion, an isolated F anion and three water mol­ecules of solvation. Each [FeF6]3− anion is surrounded by four separate hydrogen-bonded water mol­ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N—H...F hydrogen bonds, resulting in a three-dimensional structure.
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