organic compounds
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In the title compound, C11H5I2N, the two iodine-atom substitutents with their large atomic sizes lead to short intramolecular IH distances (3.01 Å). In the crystal, the trisubstituted azulene system forms π-stacks [centroid–centroid distance = 3.6343 (11) Å] along the a-axis direction, showing the characteristic azulene interaction mode between the electron-rich five-membered ring and the electron-deficient seven-membered ring. II [3.9129 (2) Å] non-covalent contacts are observed along with weak C—HN and C—Hπ. bonds.