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In this distorted octa­hedral iridium complex, the three PMe3 ligands are arranged in a meridional geometry, with the chloride ion cis to all three PMe3 groups and the phenyl iso­thio­cyanate ligand bonded in an η2-fashion through the C and S atoms. The geometric parameters for the metal-complexed PhNCS group are compared with other metal-complexed phenyl iso­thio­cyanates, as well as with examples of uncomplexed aryl iso­thio­cyanates.
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