Download citation
Download citation

link to html
In the crystal structure of the title salt, C12H30N42+·2C24H20B, the C—N bond lengths in the central CN3 unit of the guanidinium ion are 1.3388 (17), 1.3390 (16) and 1.3540 (17) Å, indicating partial double-bond character in each. The central C atom is bonded to the three N atoms in a nearly ideal trigonal-planar geometry and the positive charge is delocalized in the CN3 plane. The bonds between the N atoms and the terminal C-methyl groups of the guanidinium moiety, all have values close to a typical single bond [1.4630 (16)–1.4697 (17) Å]. C—H...π inter­actions are present between the guanidinium H atoms and the phenyl C atoms of one tetra­phenyl­borate ion. The phenyl rings form a kind of aromatic pocket, in which the guanidinium ion is embedded.
Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds