organic compounds
Open access
In the title compound, C10H20N4O3, the piperazine ring adopts a chair conformation. The molecule adopts an E conformation across the C=N double bond, with the –OH group and the piperazine ring trans to one another. Further, the H atom of the hydroxy group is directed away from the NH2 group. An intramolecular N—HO contact occurs involving the NH2 group and the oxime O atom. In the crystal, molecules are linked via strong N—HO and O—HN hydrogen bonds with alternating R22(6) and C(9) motifs into tetrameric units forming R44(28) motifs.
organic compounds
Open access
In the title compound, C13H8ClF4N, the dihedral angle between the benzene and pyridine rings is 59.8 (3)°. In the crystal, molecules are stacked in columns along the b axis through weak C—Hπ interactions.