organic compounds
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The previously reported room-temperature crystal structure [Jaud Baldy, Negrel, Poite & Chanon (1993). Z. Kristallogr. 204, 289–291] of the title compound, C20H8Cl12, is monoclinic with Z′ = 1, whereas the 90 K structure reported herein is triclinic with Z′ = 2 and shows a 2% volume contraction. The crystallographically independent unit chosen consists of both enantiomers (Λ and Δ) of this propeller-like molecule. Both enantiomers display quasi-twofold symmetry, with average bond-length/bond-angle deviations of 0.0018 (4) Å and 0.41 (2)° for Λ, and 0.0026 (4) Å and 0.50 (2)° for Δ.