Cl–OH ion-exchanging process in chlorapatite (Ca₅(PO₄)₃Cl_x(OH)_1 − x) – a deep insight

E. García-Tuñón, B. Dacuña, G. Zaragoza, J. Franco and F. Guitián

Chlorapatite (ClAp) single crystals have been synthesized and described as stoichiometric with hexagonal structure. The heat treatment of these crystals at high temperature led to systematic structural modifications due to the Cl⁻ by OH⁻ anion replacement.

Keywords: chlorapatite (ClAp); ion exchanging; binary system; crystal phase transformations; structure changes.

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Cl–OH ion-exchanging process in chlorapatite (Ca5(PO4)3Clx(OH)1 − x) – a deep insight

Cl–OH ion-exchanging process in chlorapatite (Ca₅(PO₄)₃Cl_x(OH)_1 − x) – a deep insight