A candidate for a single-chain magnet: [Mn₃(OAc)₆(py)₂(H₂O)₂]_n (OAc is acetate and py is pyridine)

J. Caballero-Jiménez, Y. Reyes Ortega, S. Bernès and R. Escudero

[Mn₃(OAc)₆(py)₂(H₂O)₂]_n (OAc is acetate and py is pyridine), a candidate for a single-chain magnet, is a true one-dimensional coordination polymer, in which the Mn^II centres form a zigzag chain along [010], based on trinuclear repeat units (Mn1

Mn2

Mn2'). The structural features are compatible with a single-chain magnet behaviour, as confirmed by preliminary magnetic studies.

Keywords: crystal structure; manganese carboxylate cluster; one-dimensional polymer; qubit-based computation materials; single-molecule magnet; single-chain magnets; Ising one-dimensional system.

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A candidate for a single-chain magnet: [Mn3(OAc)6(py)2(H2O)2]n (OAc is acetate and py is pyridine)

A candidate for a single-chain magnet: [Mn₃(OAc)₆(py)₂(H₂O)₂]_n (OAc is acetate and py is pyridine)