Acta Crystallographica Section C
Acta Crystallographica
Section C
STRUCTURAL CHEMISTRY
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Acta Cryst.
(2014).
C
70
,
550-554
https://doi.org/10.1107/S2053229614009966
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A new semiconducting quaternary mixed halogenide: pentathallium dimercury pentabromide tetraiodide, Tl
5
Hg
2
Br
5
I
4
V. Pavlyuk
,
G. Dmytriv
,
M. Szyrej
,
S. Levkovets
and
O. Parasyuk
A novel semiconducting quaternary mixed halogenide, Tl
5
Hg
2
Br
5
I
4
, represents a new series of composite structures described by the general formula
n
TlBr*
m
Tl
2
[HgBr
2
I
2
].
Keywords:
crystal structure
;
quaternary phase
;
semiconductor
;
electronic structure calculations
;
TB-LMTO-ASA method
;
halogenide
.
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