Acta Crystallographica Section C
Acta Crystallographica
Section C
STRUCTURAL CHEMISTRY
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scorpionates
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Acta Cryst.
(2013).
C
69
,
959-962
https://doi.org/10.1107/S0108270113016612
Download PDF of article
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Thallium(I) complexes of fluorinated bis- and tris(pyrazolyl)borate ligands: [H
2
B{3,5-(CF
3
)
2
pz}
2
]Tl and [HB{3,5-(CF
3
)
2
pz}
3
]Tl
H. V. R. Dias
and
J. Thankamani
[H
2
B{3,5-(CF
3
)
2
pz}
2
]Tl has a two coordinate thallium atom with a bent geometry and boat-shaped bis(pyrazolyl)borate ligand. The related tris(pyrazolyl)borate analogue [HB{3,5-(CF
3
)
2
pz}
3
]Tl has a trigonal pyramidal thallium atom.
Keywords:
crystal structure
;
thallium
;
scorpionate
;
bis(pyrazolyl)borate
;
tris(pyrazolyl)borate
;
fluorinated
.
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