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N-(3,4,5-Tri­meth­oxy­benzyl­idene)naphthalen-1-amine forms simple hydrogen-bonded sheets built from C-H...O hydrogen bonds, linked by [pi]-[pi] stacking inter­actions, and its reduction product forms complex sheets built from N-H...O, C-H...O and C-H...[pi](arene) hydrogen bonds.

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The reaction of a chloro­pyrazole­carbaldehyde with phenyl­hydrazine proceeds via a simple condensation rather than substitution or cyclo­condensation. The resulting compound forms hydrogen-bonded chains, which are linked into sheets by [pi]-[pi] stacking inter­actions.

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In three 5-acetyl-11-ethyl-6,11-di­hydro-5H-dibenzo[b,e]azepine-6-carb­oxy­lic acids, which differ only in the presence of zero, one or two methyl substituents in one of the aryl rings, the hydrogen-bonded supra­molecular aggregation is, respectively, two-, one- and three-dimensional.

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Four related compounds exemplify the reaction sequence from a 1,4-ep­oxy­benzazepine ester via its reduction product, a benzazepin-4-ol ester, and the corresponding hy­droxy carb­oxy­lic acid, to a lactone as formed by intra­molecular condensation.

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