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The asymmetric unit of the title compound, (C7H8N4)2[CoCl4]·H2O, contains one [CoCl4]2- anion, two 5,7-dimethyl-1,2,4-triazolo[1,5-a]pyrimidinium cations monoprotonated at the N atom at position 3 and one uncoordinated water mol­ecule. Hydrogen bonds define infinite chains along the a axis, which link together all residues.
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