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In the crystal structure of the title compound, C6H6IN, each 2-iodo­aniline mol­ecule forms part of three extended helices. Each helix exhibits a different inter­molecular inter­action, viz. weak N—H...N hydrogen bonds with an H...N distance of 2.31 (11) Å, I...I inter­actions of 3.7986 (15) Å and C—H...π contact distances of 2.53 Å.

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In the crystal structure of the title compound, C13H10O3, the mol­ecules form classical hydrogen-bonded carboxylic acid dimers [O...O = 2.651 (2) Å]. These dimers are linked by C—H...π and π–π inter­actions to give a three-dimensional network.
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