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In the crystal structure of the title compound, [Fe2(C12H10P)2(CO)6]·CH2Cl2, the complex mol­ecule lies across a mirror plane. Two diphosphide ligands bridge two (CO)3Fe fragments to form a dinuclear complex, in which the Fe—Fe distance is 2.6701 (6) Å. Two aromatic rings within the same molecule inter­act by face-to-face π–π stacking, with a centroid-to-centroid distance of 3.601 (2) Å.
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