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In the title compound, 2Na+·C8H11O10·NO3, the NaI atom is heptacoordinate with an approximately pentagonal–bipyramidal geometry. A possible strong symmetric hydrogen bond, with the H atom located at an inversion centre and an O...O distance of 2.450 (2) Å, is observed in the crystal structure.

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2,3,3',4'-Tetra­methyl­biphen­yl, C16H18, was synthesized in a palladium-catalysed boronic acid cross-coupling reaction. In the solid state, these weakly inter­acting unsymmetrical mol­ecules show an apparent dimerization of the ortho-dimethyl­phen­yl groups, a packing motif that is seen in a significant number of other ortho-dimethyl­phen­yl-containing compounds.
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