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In the title compound, [Nd(NO3)3(C26H38N2O4)]·C3H6O, the NdIII atom is coordinated by ten O atoms in a a distorted bicapped dodecahedral geometry. The Nd-O(carbonyl) bond distances [average 2.3817 (18) Å] are significantly shorter than other Nd-O bonds in the NdIII complex.

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In the title compound, [Ce(NO3)3(C22H30N2O4)(H2O)]·CH3CN, the CeIII atom is coordinated by 11 O atoms in a distorted monocapped penta­gonal antiprismatic geometry. The Ce-O(carbon­yl) bond distances [average 2.415 (3) Å] are significantly shorter than the other Ce-O bonds [2.495 (3)-2.931 (3) Å] in the complex.
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