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The title compound, [Cu2(bnpp)2(bpa)2](ClO4)2·0.5CH3CN [bpa is bis­(2-pyridylmeth­yl)amine (C12H13N3) and bnpp is bis­(4-nitro­phen­yl)phosphate (C12H8N2O8P)], contains two CuII ions, each coordinated in a distorted square-pyramidal geometry formed by the tridentate chelating ligand bpa and two O-atom donors from two bnpp ligands. Two bnpp anions bridge two CuII ions to form the dinuclear complex cation, one O-atom donor of each bnpp coordinating in a basal site and another coordinating in the apical position with a Jahn–Teller elongated bond of 2.189 (4) or 2.244 (3) Å.
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