metal-organic compounds
The title compound, [Cu2(bnpp)2(bpa)2](ClO4)2·0.5CH3CN [bpa is bis(2-pyridylmethyl)amine (C12H13N3) and bnpp is bis(4-nitrophenyl)phosphate (C12H8N2O8P)], contains two CuII ions, each coordinated in a distorted square-pyramidal geometry formed by the tridentate chelating ligand bpa and two O-atom donors from two bnpp ligands. Two bnpp anions bridge two CuII ions to form the dinuclear complex cation, one O-atom donor of each bnpp coordinating in a basal site and another coordinating in the apical position with a Jahn–Teller elongated bond of 2.189 (4) or 2.244 (3) Å.