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The title compound, C14H28N2O5S, was synthesized by the reaction of 2-[(methyl­sulfan­yl)meth­yl]oxirane with di-tert-butyl oxalate in hydrazine hydrate. In the crystal, mol­ecules are linked by N—H...O and O—H...O hydrogen bonds into supra­molecular chains propagating along the b-axis direction.
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