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The title zwitterion,, C16H11ClN2O, is approximately planar, the dihedral angle between the benzene ring and naphthalene ring system is 1.55 (13)°; an intra­molecular N—H...O hydrogen bond stabilizes the planar conformation. In the crystal, π–π stacking between the benzene ring and the naphthalene ring system of adjacent mol­ecules links the mol­ecules into supra­molecular chains running along the b axis, the centroid–centroid distance being 3.765 (2) Å.

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In the title zwitterion, C17H12N2O2, the dihedral angle between the benzene ring and naphthalene ring system is 11.76 (7)° and an intra­molecular N—H...O hydrogen bond exists. In the crystal, molecules are linked via pairs of C—H...O hydrogen bonds, forming inversion dimers.
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