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In the title coordination polymer, [Ag2Cl2(C10H8N2)(C18H15P)2]n, the AgI cation is coordinated by a 4,4′-bi­pyridine N atom, a tri­phenyl­phosphane P atom and two Cl anions in a distorted tetra­hedral geometry. The 4,4-bi­pyridine and Cl anions bridge the AgI cations, forming polymeric chains running along [21-1]. In the crystal, weak C—H...Cl inter­actions link the polymeric chains into a three-dimensiona supra­molecular architecture.
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