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The title compound, 2C5H7N52+·2HSO4·SO42−, was synthesized from adenine and sulfuric acid. The asymmetric unit contains two diprotonated adeninium cations, two bis­ulfate anions and one sulfate anion. The crystal structure is stabilized by classical N—H...O and O—H...O hydrogen bonds, and weak C—H...O and C—H...N hydrogen bonds, generating a three-dimensional network.
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