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In the title VIV complex, [VO(C13H15NO3)(C12H8N2)], the oxidovanadium cation is N,N′-chelated by a 1-10-phenanthroline ligand and N,O,O′-chelated by a Schiff base anion in a distorted octa­hedral geometry. Weak inter­molecular C—H...O hydrogen bonds occur in the crystal structure which contains solvent-accessible voids of 81 Å3.
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