organic compounds
Open access
In the title compound, C14H11ClN2O4·CH3OH, the molecule adopts an E conformation about the C=N bond. The compound is in the enamine–keto form. The two terminal benzene rings make a dihedral angle of 10.53 (9)°. Intra-molecular O—HO and O—HN hydrogen bonding stabilizes the molecular structure. In the crystal, O—HO hydrogen bonds link the molecules, forming chains running along the b axis.
organic compounds
Open access
In the title compound, C13H12O2, the dihedral angle between the pyranone and phenyl rings is 57.55 (9)°. In the crystal, the molecules are linked by π–π stacking interactions between the parallel pyranone rings of neighboring molecules with distances of 3.5778 (11) Å and 3.3871 (11) Å between the planes. C—HO interactions also occur.