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In the title complex, {[Nd(C6H4NO2)2(H2O)4]Cl}n, the NdIII cation is located on a twofold rotation axis and coordinated by four isonicotiniate anions and four water mol­ecules in a distorted square-anti­prismatic geometry. The carboxyl­ate groups of the isonicotinate anions bridge the NdIII cations, forming polymeric chains running along the c axis. The Cl anion is located on a twofold rotation axis and is linked to the polymeric chains via O—H...Cl hydrogen bonding. Inter­molecular O—H...O and O—H...N hydrogen bonds are also present in the crystal structure.
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