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In the crystal structure of the title complex, [Cd(C2N3)2(C8H10N4)]n or [Cd(dca)2(bim)]n, where dca is dicyanamide and bim is 1,2-bis­(imidazol-1-yl)ethane, each CdII atom is in a distorted octa­hedral environment. Four N atoms from four dca ligands occupy the equatorial positions, and two N atoms from two bim ligands occupy the axial positions. Each CdII atom is situated at a center of symmetry, and a twofold axis runs through the mid-points of the bim exocyclic C—C bond and the Cd...Cd vector. The structure consists of chains in which neighboring CdII atoms are connected through one bim and two end-to-end dca bridges.
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